Syntheses and Enantioselective Recognition of Chiral Poly(phenylacetylene)s bearing Bulky Optically Active Menthyl Groups

• Shinohara, Ken-ichi

• Aoki, Toshiki

• Kaneko, Takashi

• Oikawa, Eizo

抄録

Two optically active poly(menthoxycarbonylphenyleneethynylene)s were synthesized by polycondensation using a palladium-copper catalyst system. All polymers showed Cotton effects in the absorption region of the main chain, meaning that chirality is induced to the main chain. Moreover, these chiral polymers showed the enantioselective recognition ability for chiral menthol in CD spectra.

identifier:https://dspace.jaist.ac.jp/dspace/handle/10119/4947

収録刊行物

• Polymer

  Polymer 42 (1), 351-355, 2001-01

  Elsevier

キーワード

• Poly(phenyleneethynylene)
• Menthyl Group
• Enantioselectivite Recognition

詳細情報

• CRID: 1050001337537197824
• NII論文ID: 120000861718
• ISSN: 00323861
• Web Site: http://hdl.handle.net/10119/4947
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles