New organic activators for the enantioselective reduction of aromatic imines with trichlorosilane

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抄録

N-Picolinoyl-(2S)-(diphenylhydroxymethyl)pyrrolidine was found to work as an organic activator in the reduction of aromatic imines to the corresponding amines by Cl3SiH. The highest selectivity was 80% ee. These are the first data showing that N-formyl group is not always essential as N-protecting group of pyrrolidine derivatives for the reduction of imines by Cl3SiH.

収録刊行物

  • Tetrahedron Letters

    Tetrahedron Letters 47(22), 3751-3754, 2006-05-29

    Elsevier

各種コード

  • NII論文ID(NAID)
    120000916326
  • 本文言語コード
    ENG
  • 資料種別
    journal article
  • ISSN
    0040-4039
  • データ提供元
    IR 
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