Poly[bis(acetone)bis[μ-4-[(5-chloro-2-oxidophenyl)diazenyl]-3-oxido-N-phenylnaphthalene-2-carboxamidato]sodium(I)ferrate(III)]

• Mizuguchi, Jin

• Sato, Yohei

• Uta, Kazuya

抄録

The title compound, [FeNa(C23H14ClN3O3)2(C3H6O)2]n, has a skeleton of an azo-FeIII anion complex with a sodium cation, used widely as a charge-control agent (CCA) of the negative type in electrophotography. In the FeIII anion-complex, the FeIII atom is coordinated by four carbonyl O atoms and two N atoms of the diazo groups from two azo ligands lying cis to each other. There are two N-HO intramolecular hydrogen bonds between the NH group and the carbonyl O atom. In the crystal structure, there exists a sodium-cation dimer bridged by the carbonyl O atoms at the periphery of the anion complex. An interesting aspect of this structure is that each sodium cation unites three different Fe-anion complexes through the carbonyl O atom, generating a quasi-two-dimensional network parallel to the (001) plane. At the same time, the sodium cation accommodates two acetone molecules, linked through the carbonyl O atom.

収録刊行物

• Acta Crystallographica Section E: Structure Reports Online

  Acta Crystallographica Section E: Structure Reports Online 63 (Part 5), m1377-m1378, 2007-05

  International Union of Crystallography

キーワード

• single-crystal X-ray study
• T = 93 K
• mean σ(C–C) = 0.004 Å
• R factor = 0.056
• wR factor = 0.163
• data-to-parameter ratio = 21.9.

詳細情報

• CRID: 1050564287692499456
• NII論文ID: 120000922693
• NII書誌ID: AA12097683
• ISSN: 16005368
• Web Site: http://hdl.handle.net/10131/3200
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
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