A cross-metathesis approach to the stereocontrolled synthesis of the AB ring segment of ciguatoxin

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Abstract

<p>Synthesis of the AB ring segments of ciguatoxin is described. The present synthesis includes a Lewis acid mediated cyclization of allylstannane with aldehyde, cross-metathesis reaction introducing the side chain, and Grieco-Nishizawa dehydration on the A ring.</p>

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