Lactone Carboxylic Acids. III. Reaction of Ethyl β-Alkylglycidates with Ethyl Malonate

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Abstract

The ring opening of epoxide group in the reaction of ethyl ,β-alkylglycidates with sodiomalonate was observed mostly at the α-position of the glycidates. Ethyl β-ethylglycidate, however, on treatment with sodiomalonate gave ten percent of β-fission product, elucidated by NMR spectra. The reaction sequence provides a general preparative route to γ-alkylparaconic acids and their derivatives.

Journal

  • Memoirs of the School of Engineering, Okayama University

    Memoirs of the School of Engineering, Okayama University 2(1), 74-79, 1967-04-01

    岡山大学工学部

Codes

  • NII Article ID (NAID)
    120002307843
  • NII NACSIS-CAT ID (NCID)
    AA00733903
  • Text Lang
    ENG
  • Article Type
    departmental bulletin paper
  • ISSN
    0475-0071
  • Data Source
    IR 
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