Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes

HANDLE Open Access

Abstract

Iridium complexes generated from [Ir(OMe)(COD)]2 and tris[3,5-bis(trifluoromethyl)phenyl]phosphine efficiently catalyzed the ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron in octane at 80℃ to produce the corresponding arylboronates in high yields with excellent regioselectivities.

Journal

Details 詳細情報について

  • CRID
    1050001339002324352
  • NII Article ID
    120002695774
  • HANDLE
    2115/44631
  • ISSN
    13597345
  • Text Lang
    en
  • Article Type
    journal article
  • Data Source
    • IRDB
    • CiNii Articles

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