Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes
Abstract
Iridium complexes generated from [Ir(OMe)(COD)]2 and tris[3,5-bis(trifluoromethyl)phenyl]phosphine efficiently catalyzed the ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron in octane at 80℃ to produce the corresponding arylboronates in high yields with excellent regioselectivities.
Journal
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- Chemical Communications
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Chemical Communications 46 (1), 159-161, 2010-01-07
Royal Society of Chemistry
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Details 詳細情報について
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- CRID
- 1050001339002324352
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- NII Article ID
- 120002695774
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- HANDLE
- 2115/44631
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- ISSN
- 13597345
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- IRDB
- CiNii Articles