Quantum reaction boundary to mediate reactions in laser fields

• Kawai, Shinnosuke

• Komatsuzaki, Tamiki

Abstract

Dynamics of passage over a saddle is investigated for a quantum system under the effect of time-dependent external field (laser pulse). We utilize the recently developed theories of nonlinear dynamics in the saddle region, and extend them to incorporate both time-dependence of the external field and quantum mechanical effects of the system. Anharmonic couplings and laser fields with any functional form of time dependence are explicitly taken into account. As the theory is based on the Weyl expression of quantum mechanics, interpretation is facilitated by the classical phase space picture, while no "classical approximation" is involved. We introduce a quantum reactivity operator to extract the reactive part of the system. In a model system with an optimally controlled laser field for the reaction, it is found that the boundary of the reaction in the phase space, extracted by the reactivity operator, is modulated with time by the effect of the laser field, to "catch" the system excited in the reactant region, and then to "release" it into the product region. This method provides new insights in understanding the origin of optimal control of chemical reactions by laser fields.

Journal

• Journal of Chemical Physics

  Journal of Chemical Physics 134 (2), 024317-, 2011-01-14

  American Institute of Physics

Details

• CRID: 1050282813983946112
• NII Article ID: 120002834746
• HANDLE: 2115/44992
• ISSN: 00219606
• Text Lang: en
• Article Type: journal article
• Data Source:
  • IRDB
  • CiNii Articles