Rhenium-catalyzed insertion of terminal alkenes into a C(sp(2))–H bond and successive transfer hydrogenation

• Kuninobu, Yoichiro

• Nakahara, Takahiro

• Yu, Peng

• Takai, Kazuhiko

抄録

Treatment of aromatic aldimines with terminal alkenes in the presence of a rhenium catalyst, [HRe(CO)(4)](n), gives 2-alkenylbenzylamines in good to excellent yields. This reaction proceeds via the insertion of the alkene into a C-H bond at the ortho-position of the imino group of the aromatic aldimine followed by sequential beta-hydride elimination from the formed alkyl rhenium intermediate and then by hydrogenation of the imino group of the aldimine.

収録刊行物

• Journal of Organometallic Chemistry

  Journal of Organometallic Chemistry 696 (1), 348-351, 2011-01-01

  Elsevier Science SA.

キーワード

• Rhenium
• Insertion
• Hydrogen transfer
• Aldimine
• Alkene

詳細情報

• CRID: 1050846637416654976
• NII論文ID: 120003497018
• NII書誌ID: AA00704122
• ISSN: 0022328X
• Web Site: https://ousar.lib.okayama-u.ac.jp/46985
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles