Chemically Etched Sharpened Tip of Transparent Crystallized Glass Fibers with Nonlinear Optical Ba2TiSi2O8 Nanocrystals
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- ENOMOTO Itaru
- Department of Materials Science and Technology, Nagaoka University of Technology
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- BENINO Yasuhiko
- Department of Materials Science and Technology, Nagaoka University of Technology
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- FUJIWARA Takumi
- Department of Applied Physics, Graduate School of Engineering, Tohoku University
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- KOMATSU Takayuki
- Department of Materials Science and Technology, Nagaoka University of Technology
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Glass fibers with a diameter of~100 μm are drawn by just pulling up melts of 40BaO•20TiO2•40SiO2 glass, and transparent crystallized glass fibers consisting of nonlinear optical fresnoite Ba2TiSi2O8 nanocrystals (particle size:~100-200 nm) are fabricated by crystallization of glass fibers. Precursor glass fibers and nanocrystallized glass fibers are etched chemically using a meniscus method, in which an etching solution of 0.1 wt%-HF/hexane is used. Glass fibers with sharpened tips (e.g., the taper length is~L=200 μm and the tip angle is~θ=23°) are obtained. It is found that etched nanocrystallized glass fibers also have sharpened tips (L=50 μm, θ=80°). Compared with precursor glass fibers, nanocrystallized glass fibers show a high resistance against chemical etching in a 0.1 wt%HF solution. Although sharpened tips in nanocrystallized glass fibers do not have nanoscaled apertures, the present study suggests that nanocrystallized glass fibers showing second harmonic generations would have a potential for fiber-type light control optical devices.<br>
収録刊行物
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- Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
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Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌) 115 (1342), 374-378, 2007
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390282680255210240
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- NII論文ID
- 110006279036
- 120003728487
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- NII書誌ID
- AN10040326
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- ISSN
- 18821022
- 09145400
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- HANDLE
- 10097/52032
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- NDL書誌ID
- 8846863
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- IRDB
- NDL
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