Cyanide bridged tetranuclear complex with a novel terthiophene based ligand

Access this Article

Search this Article

Abstract

A new terthiophene based ligand (L = 3-(2-pryridyl)-5-(2,2′:5′,2″-terthien-3′-yl) pyrazole was synthesized. The reaction of Ni(BF4)2·6H2O, L and nBu4N[Fe(CN)3tp∗] (tp∗ = tris(3,5-dimethylpyrazol-1-yl)borohyrdide) with NaBPh4 in MeOH/acetone yielded a cyanide bridged tetranuclear complex [Fe2Ni2(CN)6(tp∗)2(L)4](BPh4)2 (1). The electrochemical properties of both 1 and L were investigated, and magnetic susceptibility measurements of 1 were conducted, revealing that ferromagnetic interactions were operative within the tetranuclear core.

Journal

  • Polyhedron

    Polyhedron 30(18), 3245-3248, 2011-11

    Elsevier Ltd.

Codes

  • NII Article ID (NAID)
    120003874835
  • NII NACSIS-CAT ID (NCID)
    AA10531370
  • Text Lang
    ENG
  • Article Type
    journal article
  • ISSN
    0277-5387
  • Data Source
    IR 
Page Top