Rhodium-catalyzed asymmetric phenylation of N-phosphinoylarylimines with triphenylborane

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Abstract

Triphenylborane asymmetrically transfers its phenyl group to N-diphenylphosphinoylarylimines to give diarylmethylamines with high ee in high yield without imine hydrolysis under the catalysis of a chiral amidomonophosphane–rhodium(I) complex.

Journal

  • Catalysis Science & Technology

    Catalysis Science & Technology 1(1), 62-64, 2011-02

    Royal Society of Chemistry

Codes

  • NII Article ID (NAID)
    120004205184
  • Text Lang
    ENG
  • Article Type
    journal article
  • ISSN
    2044-4753
  • Data Source
    IR 
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