Rhodium-catalyzed asymmetric phenylation of N-phosphinoylarylimines with triphenylborane
Access this Article
Author(s)
Abstract
Triphenylborane asymmetrically transfers its phenyl group to N-diphenylphosphinoylarylimines to give diarylmethylamines with high ee in high yield without imine hydrolysis under the catalysis of a chiral amidomonophosphane–rhodium(I) complex.
Journal
-
- Catalysis Science & Technology
-
Catalysis Science & Technology 1(1), 62-64, 2011-02
Royal Society of Chemistry