Transition metal-catalyzed borylation of alkanes and arenes via C-H activation

• Ishiyama, Tatsuo

• Miyaura, Norio

Abstract

Since 1999, direct borylation of hydrocarbons catalyzed by a transition metal complex has been extensively studied by several groups and has become an economical, efficient, elegant, and environmentally benign protocol for the synthesis of a variety of organoboron compounds. Re-, Rh-, Ir- and Pd-catalyzed C -H borylation of alkanes, arenes and benzylic positions of alkylarenes by bis(pinacolato)diboron or pinacolborane provide alkyl-, aryl-, heteroaryl- and benzylboron compounds, respectively. In this review, seminal early works and exciting recent developments in the area of direct borylation of hydrocarbons via C -H activation are summarized.

Journal

• Journal of Organometallic Chemistry

  Journal of Organometallic Chemistry 680 (1-2), 3-11, 2003-08-29

  Elsevier

Keywords

• Transition metal complexes
• Bis(pinacolato)diboron
• Pinacolborane
• Hydrocarbon
• Organoboron compound
• C -H borylation

Details

• CRID: 1050564288970171776
• NII Article ID: 120005438243
• HANDLE: 2115/56230
• ISSN: 0022328X
• Text Lang: en
• Article Type: journal article
• Data Source:
  • IRDB
  • CiNii Articles