Oxidative kinetic resolution of racemic alkyl aryl carbinols by an electronically tuned chiral nitroxyl radical

• Hamada, Shohei

• Wada, Yoshiyuki

• Sasamori, Takahiro

• Tokitoh, Norihiro

• Furura, Takumi

• 川端, 猛夫

抄録

A method for oxidative kinetic resolution of racemic alcohols catalyzed by chiral nitroxyl radical (R, R)-1 has been developed. This method is especially effective for the kinetic resolution of tert-butyl aryl carbinols (s = up to 23).

収録刊行物

• Tetrahedron Letters

  Tetrahedron Letters 55 (11), 1943-1945, 2014-03

  Elsevier Ltd.

キーワード

• Nitroxyl radical
• Oxidation
• Kinetic resolution
• Alcohols
• Hydride shift

詳細情報

• CRID: 1050282810770822912
• NII論文ID: 120005439590
• NII書誌ID: AA00861801
• ISSN: 00404039
• HANDLE: 2433/187855
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles