Iron oxide catalyzed reduction of acid chlorides to aldehydes with hydrosilanes

• Cong, Cong

• Fujihara, Tetsuaki

• Terao, Jun

• Tsuji, Yasushi

Abstract

Iron-catalyzed reduction of acid chlorides to the corresponding aldehydes with a hydrosilane as a reducing agent has been developed. A simple mixture of a commercially available iron oxide (FeO) and tris(2, 4, 6-trimethoxyphenyl)phosphine (TMPP) as a catalyst realized the reduction of acid chlorides to the corresponding aldehydes under mild reaction conditions.

Journal

• Catalysis Communications

  Catalysis Communications 50 25-28, 2014-05-05

  Elsevier B.V.

Keywords

• Acid chlorides
• Aldehydes
• Hydrosilanes
• Iron oxide
• Reduction

Details

• CRID: 1050564285744932352
• NII Article ID: 120005466662
• ISSN: 15667367
• DOI: 10.1016/j.catcom.2014.02.018
• HANDLE: 2433/187076
• Web Site: https://api.elsevier.com/content/article/PII:S1566736714000752?httpAccept=text/xml
• Web Site: https://api.elsevier.com/content/article/PII:S1566736714000752?httpAccept=text/plain
• Text Lang: en
• Article Type: journal article
• Data Source:
  • IRDB
  • Crossref
  • CiNii Articles
  • KAKEN