Reactions of organolithiums with dialkyl oxalates. A flow microreactor approach to synthesis of functionalized α-keto esters.

• Nagaki, Aiichiro

• Ichinari, Daisuke

• Yoshida, Jun-ichi

Abstract

Reactions of functionalized aryllithiums with dialkyl oxalates were achieved using a flow microreactor to obtain α-keto esters with high selectivity by virtue of fast 1 : 1 micromixing.

Journal

• Chemical communications

  Chemical communications 49 (31), 3242-3244, 2013-04-21

  Royal Society of Chemistry

Keywords

• Bromobenzenes/chemistry
• Esters
• Lithium/chemistry
• Organometallic Compounds/chemistry
• Oxalates/chemistry
• Temperature

Details

• CRID: 1050564285744937344
• NII Article ID: 120005466674
• NII Book ID: AA11071130
• ISSN: 13597345
• HANDLE: 2433/187101
• Text Lang: en
• Article Type: journal article
• Data Source:
  • IRDB
  • CiNii Articles