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Abstract

The aminopalladation of amino allylic alcohol using Cl2Pd(MeCN)(2) in CH2Cl2 gave the 2,6-disubstituted piperidine with excellent diastereoselectivity. This compound was successfully converted into (+)-azimine (1) using cross-metathesis and Shiina macrolactonization.

Journal

  • TETRAHEDRON

    TETRAHEDRON 69(39), 8349-8352, 2013-09-30

    PERGAMON-ELSEVIER SCIENCE LTD

Codes

  • NII Article ID (NAID)
    120005468439
  • NII NACSIS-CAT ID (NCID)
    AA00861787
  • Text Lang
    ENG
  • Article Type
    journal article
  • ISSN
    0040-4020
  • Data Source
    IR 
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