Redox active dendronized polystyrenes equipped with peripheral triarylamines.

• Nokami, Toshiki

• Musya, Naoki

• Morofuji, Tatsuya

• Takeda, Keiji

• Takumi, Masahiro

• Shimizu, Akihiro

• 吉田, 潤一

抄録

Dendronized polystyrene having peripheral bromo groups was prepared from the dendronization of unfunctionalized polystyrene with dendritic diarylcarbenium ions bearing peripheral bromo groups using the "cation pool" method. The palladium-catalyzed amination of the peripheral bromo groups with diarylamine gave dendronized polystyrene equipped with peripheral triarylamines, which exhibited two sets of reversible redox peaks in the cyclic voltammetry curves.

収録刊行物

• Beilstein journal of organic chemistry

  Beilstein journal of organic chemistry 10 3097-3103, 2014-12-22

  Beilstein-Institut.

キーワード

• carbocation
• cross-coupling
• dendrimer
• dendronized polymer
• redox

詳細情報

• CRID: 1050845760732673792
• NII論文ID: 120005540401
• ISSN: 18605397
• HANDLE: 2433/193680
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles