Formal [4+2] reaction between 1,3-diynes and pyrroles: gold(I)-catalyzed indole synthesis by double hydroarylation.

• Matsuda, Yuka

• Naoe, Saori

• Oishi, Shinya

• 藤井, 信孝

• 大野, 浩章

抄録

Indole synthesis by a gold(I)-catalyzed intermolecular formal [4+2] reaction between 1, 3-diynes and pyrroles has been developed. This reaction involves the hydroarylation of 1, 3-diynes with pyrroles followed by an intramolecular hydroarylation to give the 4, 7-disubstituted indoles. This reaction can also be applied to the synthesis of carbazoles when indoles are used as the nucleophiles instead of pyrroles.

収録刊行物

• Chemistry : A European Journal

  Chemistry : A European Journal 21 (4), 1463-1467, 2014-11-28

  Wiley

キーワード

• carbazoles
• cascade reaction
• gold catalysis
• hydroarylation
• indoles

詳細情報

• CRID: 1050282810790109696
• NII論文ID: 120005613671
• NII書誌ID: AA11076269
• ISSN: 09476539
• ISSN: 15213765
• HANDLE: 2433/198281
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles