Palladium-Catalyzed Amination of Aryl Sulfides with Aliphatic Amines

• Gao, Ke

• 依光, 英樹

• Osuka, Atsuhiro

抄録

Conditions for the palladium–NHC-catalyzed amination of aryl sulfides with aliphatic as well as aromatic amines were established. The KHMDS-mediated amination of heteroaryl sulfides could proceed without palladium. Based on the distinct difference in reactivity of C–Br and C–S bonds, a sequential amination of bromothioanisole can take place to install two different alkylamino groups onto the aromatic ring in one pot.

収録刊行物

• European Journal of Organic Chemistry

  European Journal of Organic Chemistry 2015 (12), 2678-2682, 2015-03-06

  wiley

キーワード

• Synthetic methods
• Homogeneous catalysis
• Amination
• Arylation
• Sulfur
• Carbene ligands
• Palladium

詳細情報

• CRID: 1050282810790148736
• NII論文ID: 120005615643
• NII書誌ID: AA1118165X
• ISSN: 1434193X
• HANDLE: 2433/198449
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles