Copper-catalyzed borylative allyl-allyl coupling reaction.

HANDLE Open Access

Abstract

Borylative allyl-allyl coupling using allenes, bis(pinacolato)diboron, and allyl phosphates has been developed in the presence of a copper catalyst bearing an N-heterocyclic carbene ligand. The reaction affords boryl-substituted 1, 5-diene derivatives in good to high yields with high regioselectivity and Z selectivity.

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Keywords

Details 詳細情報について

  • CRID
    1050564285767008896
  • NII Article ID
    120005649312
  • ISSN
    15213773
  • HANDLE
    2433/199670
  • Text Lang
    en
  • Article Type
    journal article
  • Data Source
    • IRDB
    • CiNii Articles

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