Synthesis of 3,3-disubstituted indoline-2-thiones catalysed by an N-heterocyclic carbene.

• Ikota, Hideo

• Ishida, Takayuki

• 塚野, 千尋

• 竹本, 佳司

抄録

A catalytic method has been developed for construction of indoline-2-thiones containing an all-carbon quaternary centre at the C-3 position. Successive treatment of α, β-unsaturated aldehydes bearing an isothiocyanato moiety with an in situ generated N-heterocyclic carbene and an appropriate heteroatomic nucleophile provided the 3, 3-disubstituted indoline derivatives in moderate to good yields.

収録刊行物

• Chemical communications

  Chemical communications 50 (64), 8871-8874, 2014-06-16

  Royal Society of Chemistry

キーワード

• Aldehydes/chemistry
• Catalysis
• Indoles/chemistry
• Methane/analogs & derivatives
• Methane/chemistry
• Thiones/chemistry

詳細情報

• CRID: 1050845760743767936
• NII論文ID: 120005651943
• NII書誌ID: AA0012789X
• ISSN: 05776058
• HANDLE: 2433/199886
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles