Electrophilic iodine(I) compounds induced semipinacol rearrangement via C-X bond cleavage.

• Tsuji, Nobuya

• 小林, 祐輔

• 竹本, 佳司

抄録

Neutral electrophilic iodine(I) species proved to be efficient reagents for C-X bond cleavage of various cyclic and acyclic α-silyloxyhalides, and the induced desilylative semipinacol rearrangement provided the corresponding ketones in good yields. The reaction is operationally simple, and proceeds under mild conditions with good functional group compatibility. Mechanistic investigations, including computational studies, were also performed.

収録刊行物

• Chemical communications

  Chemical communications 50 (89), 13691-13694, 2014-09-16

  Royal Society of Chemistry

キーワード

• Bromides/chemistry
• Chlorides/chemistry
• Cyclohexenes/chemistry
• Iodine Compounds/chemistry
• Static Electricity

詳細情報

• CRID: 1050001335816176128
• NII論文ID: 120005657915
• NII書誌ID: AA11071130
• ISSN: 13597345
• HANDLE: 2433/200200
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles