Ni-Catalyzed Synthesis of Fluoroarenes via [2+2+2] Cycloaddition Involving α-Fluorine Elimination

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抄録

A method for direct synthesis of tetrasubstituted fluoroarenes via nickel-catalyzed [2+2+2] cycloaddition is presented. The reaction combines one molecule of 1,1-difluoroethylene with two molecules of alkynes and involves sequential cleavage of the C[BOND]F and C[BOND]H bonds in difluoroethylene. The catalytic cycle is established by reduction of the intermediary NiII fluoride with a triethylborane-based borate.

収録刊行物

  • Chemistry : a European journal

    Chemistry : a European journal 21(38), 13225-13228, 2015-09

    WILEY-VCH

キーワード

各種コード

  • NII論文ID(NAID)
    120005669427
  • NII書誌ID(NCID)
    AA11076269
  • 本文言語コード
    ENG
  • 資料種別
    journal article
  • ISSN
    0947-6539
  • データ提供元
    IR 
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