A chiral phosphoric acid catalyst for asymmetric construction of 1,3-dioxanes.
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Abstract
A novel method of enantioselective 1, 3-dioxane construction via a hemiacetalization/intramolecular oxy-Michael addition cascade by a chiral phosphoric acid catalyst was developed. The product was successfully transformed into an optically active 1, 3-polyol motif, indicating that the proposed reaction can provide useful chiral building blocks for the de novo synthesis of polyketides.
Accepted 09 Jun 2015
Journal
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- Chemical communications
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Chemical communications 51 (58), 11693-11696, 2015-06-12
Royal Society of Chemistry
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Details 詳細情報について
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- CRID
- 1050001335816340864
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- NII Article ID
- 120005670882
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- NII Book ID
- AA11071130
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- ISSN
- 13597345
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- HANDLE
- 2433/201598
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- IRDB
- CiNii Articles