A chiral phosphoric acid catalyst for asymmetric construction of 1,3-dioxanes.

HANDLE Open Access

Search this article

Abstract

A novel method of enantioselective 1, 3-dioxane construction via a hemiacetalization/intramolecular oxy-Michael addition cascade by a chiral phosphoric acid catalyst was developed. The product was successfully transformed into an optically active 1, 3-polyol motif, indicating that the proposed reaction can provide useful chiral building blocks for the de novo synthesis of polyketides.

Accepted 09 Jun 2015

Journal

Details 詳細情報について

  • CRID
    1050001335816340864
  • NII Article ID
    120005670882
  • NII Book ID
    AA11071130
  • ISSN
    13597345
  • HANDLE
    2433/201598
  • Text Lang
    en
  • Article Type
    journal article
  • Data Source
    • IRDB
    • CiNii Articles

Report a problem

Back to top