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Abstract

Article first published online: 14 JUL 2015Simultaneous manipulation of both spin and charge is a crucial issue in magnetic conductors. We report on a strong correlation between magnetism and conductivity in the iodine-bonded molecular conductor (DIETSe)2 FeBr2 Cl2 [DIETSe=diiodo(ethylenedithio)tetraselenafulvalene], which is the first molecular conductor showing a large hysteresis in both magnetic moment and magnetoresistance associated with a spin-flop transition. Utilizing a mixed-anion approach and iodine bonding interactions, we tailored a molecular conductor with random exchange interactions exhibiting unforeseen physical properties.

Journal

  • Angewandte Chemie

    Angewandte Chemie 54(35), 10169-10172, 2015-08-24

    ailey

Codes

  • NII Article ID (NAID)
    120005674647
  • Text Lang
    ENG
  • Article Type
    journal article
  • ISSN
    1521-3773
  • Data Source
    IR 
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