Unconventional Magnetic and Resistive Hysteresis in an Iodine-Bonded Molecular Conductor.
Abstract
Simultaneous manipulation of both spin and charge is a crucial issue in magnetic conductors. We report on a strong correlation between magnetism and conductivity in the iodine-bonded molecular conductor (DIETSe)2 FeBr2 Cl2 [DIETSe=diiodo(ethylenedithio)tetraselenafulvalene], which is the first molecular conductor showing a large hysteresis in both magnetic moment and magnetoresistance associated with a spin-flop transition. Utilizing a mixed-anion approach and iodine bonding interactions, we tailored a molecular conductor with random exchange interactions exhibiting unforeseen physical properties.
Article first published online: 14 JUL 2015
Journal
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- Angewandte Chemie
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Angewandte Chemie 54 (35), 10169-10172, 2015-08-24
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Details 詳細情報について
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- CRID
- 1050564285772192896
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- NII Article ID
- 120005674647
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- ISSN
- 15213773
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- HANDLE
- 2433/202051
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- IRDB
- CiNii Articles