Direct preparation and conversion of copper hydroxide-based monolithic xerogels with hierarchical pores

• Fukumoto, Shotaro

• 中西, 和樹

• Kanamori, Kazuyoshi

抄録

Copper hydroxide-based monolithic xerogels with controlled hierarchical pores have been prepared directly by a sol–gel process from an ionic precursor, CuCl[2]·2H[2]O. Propylene oxide acts as a gelation inducer by increasing pH homogeneously in a reaction solution. Poly(acrylamide) is utilized not only to control macroscopic phase separation but also to support the network physically. Glycerol contributes to the formation of monolithic gels by suppressing the growth of copper hydroxide crystals. An appropriate starting composition leads to co-continuous gel skeletons and macropores. Although the as-dried gels were amorphous, post-treatments (calcination and solvothermal treatment) formed metallic copper and copper oxides (CuO and Cu[2]O) without the collapse of the monolithic form and macrostructure.

Accepted 03 Jun 2015

収録刊行物

• New Journal of Chemistry

  New Journal of Chemistry 39 (9), 6771-6777, 2015

  Royal Society of Chemistry

キーワード

• Materials Chemistry
• General Chemistry
• Catalysis

詳細情報

• CRID: 1050845760748928256
• NII論文ID: 120005676687
• NII書誌ID: AA10686388
• ISSN: 11440546
• ISSN: 13699261
• DOI: 10.1039/c5nj00479a
• HANDLE: 2433/202509
• Web Site: http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C5NJ00479A
• 本文言語コード: en
• 資料種別: journal article
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