Singly and doubly β-to-β platinum-bridged porphyrin dimers and their reductive eliminations

• 田中, 隆行

• 大須賀, 篤弘

• Osuka, Atsuhiro

抄録

2-Borylated porphyrins reacted with Pt(cod)Cl2 to give β-to-β platinum-bridged porphyrin dimers, which were converted to β-to-β directly linked porphyrin dimers through triphenylphosphine-mediated reductive elimination. Similar reactions of 2, 18-diborylated Ni(ii)-porphyrin and Zn(ii)-porphyrin gave the corresponding doubly β-to-β platinum-bridged porphyrin dimers. Treatment of the doubly β-to-β platinum-bridged Ni(ii)-porphyrin dimer with triphenylphosphine caused a single reductive elimination to produce a Ni(ii)-porphyrin dimer possessing a β-to-β platinum bridge and a β-to-β direct C-C bond.

収録刊行物

• Chemical Science

  Chemical Science 6 6102-6105, 2015-07-30

  Royal Society of Chemistry (RSC)

キーワード

• General Chemistry

詳細情報

• CRID: 1050282810809433600
• NII論文ID: 120005753895
• NII書誌ID: AA12555653
• ISSN: 20416539
• ISSN: 20416520
• DOI: 10.1039/c5sc02553b
• HANDLE: 2433/210581
• Web Site: http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02553B
• 本文言語コード: en
• 資料種別: journal article
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