Abstract
The total synthesis of (−)-cardiopetaline, an aconitine-type natural product, has been accomplished. Our synthesis involved a Wagner–Meerwein rearrangement of a sulfonyloxirane that enabled, in a single step, the construction of the bicyclo[3.2.1] system in the aconitine skeleton and effective introduction of oxygen functional groups at the appropriate positions.
Journal
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- Organic Letters
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Organic Letters 18 (10), 2359-2362, 2016-05-20
ACS Publications
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Details 詳細情報について
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- CRID
- 1050282813781573120
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- NII Article ID
- 120005866818
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- HANDLE
- 2237/25052
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- ISSN
- 15237060
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- IRDB
- CiNii Articles