Planar chiral desymmetrization of a two-layered cyclophane and control of dynamic helicity through the arrangement of two nonstereogenic centers
Abstract
We designed a planar chiral two-layered cyclophane, which is inherently achiral but desymmetrized by the arrangement of two nonstereogenic centers. We demonstrate the control of dynamic helicity that is generated by the helical twisting of two-layered planes in the cyclophane, where methyl and cyclohexylmethyl groups act as directing groups.
Journal
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- Chemical communications
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Chemical communications 52 (5), 1029-1031, 2015-11-17
Royal Society of Chemistry
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Details 詳細情報について
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- CRID
- 1050845763949550080
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- NII Article ID
- 120005866833
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- HANDLE
- 2115/63577
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- ISSN
- 13597345
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- IRDB
- CiNii Articles