Synthesis of Free-Base 10-Azacorroles

• Omori, Hiroto

• Hiroto, Satoru

• Shinokubo, Hiroshi

抄録

A novel synthetic protocol has been developed for free-base 10-azacorroles. Ni(0)-mediated homocoupling of nitrogen-bridged bisdipyrrin Zn(II) complexes afforded a series of free-base 5,15-diaryl-10-azacorroles in good yields. Pd(II) and Cu(II) complexes have been prepared through metalation of free-base 10-azacorroles. Optical and electrochemical properties of 10-azacorrole metal complexes can be tuned by meso-aryl substituents and central metals. Cyclic voltammetry and theoretical calculations elucidated that the central metals of 10-azacorroles significantly affected their electronic properties.

収録刊行物

• Organic Letters

  Organic Letters 18 (12), 2978-2981, 2016-06-03

  ACS Publications

キーワード

• Organic Chemistry
• Physical and Theoretical Chemistry
• Biochemistry

詳細情報

• CRID: 1050282813781578496
• NII論文ID: 120005868227
• DOI: 10.1021/acs.orglett.6b01323
• ISSN: 15237052
• ISSN: 15237060
• HANDLE: 2237/25083
• Web Site: https://nagoya.repo.nii.ac.jp/records/22905
• Web Site: https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.6b01323
• 本文言語コード: en
• 資料種別: journal article
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