Diffusion-limited characteristics of mechanically induced currents in polypyrrole/Au-membrane composites

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Abstract

A mechanically induced current (MIC) in a polypyrrole/Au-coated membrane (PPy/Au-membrane) composite with various surface morphologies was investigated, and the electrolyte conditions were determined in an electrochemical cell. A MIC was induced on porous PPy/Au-membranes with a thin layer of PPy. Conversely, relatively small MICs were observed in non-highly porous films such as freestanding films and PPy/Au-membranes with thick PPy deposits. A MIC smaller by one order of magnitude was also observed in a Au-membrane without PPy. These results indicated that the MICs was due to a charging phenomenon in both the redox and the double layer capacitances. The MIC also varied with supporting electrolyte and their concentration. The MIC was strongly reduced in solutions with diluted electrolytes and with bulky cationic electrolytes, indicating that the number and the penetration speed of mobile ions limited the magnitude of the MIC. These characteristics indicated that the MIC was essentially a diffusion limited current. A two-electrode MIC cell was also configured to investigate a power generation film in a normal saline solution, which can possibly be utilized for biomedical applications.

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