Synthesis of aggregation-induced emission-active conjugated polymers composed of group 13 diiminate complexes with tunable energy levels via alteration of central element

• Ito, Shunichiro

• Hirose, Amane

• Yamaguchi, Madoka

• Tanaka, Kazuo

• Chujo, Yoshiki

Abstract

Conjugated polymers containing boron and gallium diiminate complexes were prepared with various electron-donating comonomers via pre- and post-complexation methods, respectively. From a comparison of emission quantum yields between solution and film states, it was seen that all polymers containing group 13 elements possessed an aggregation-induced emission property. Additionally, the frontier orbital energies and the optical and electrochemical properties of the polymers can be tuned by altering a central element at the complex moieties as well as by changing a comonomer unit. In particular, it was demonstrated that the gallium atom can contribute to stabilizing the energy levels of the lowest unoccupied molecular orbitals, resulting in narrow band gaps of the conjugated polymers. This study presents the potential of gallium not only for preparing solid-state emissive conjugated polymers but also for fabricating low-band gap materials by employing the conjugated ligand.

Journal

• Polymers

  Polymers 9 2017-02-16

  MDPI AG

Keywords

• Aggregation-induced emission
• Boron
• Conjugated polymer
• Gallium

Details

• CRID: 1050564285794676224
• NII Article ID: 120005998023
• ISSN: 20734360
• HANDLE: 2433/219097
• Text Lang: en
• Article Type: journal article
• Data Source:
  • IRDB
  • CiNii Articles