Enhancing the low-energy absorption band and charge mobility of antiaromatic Ni^II norcorroles by their substituent effects

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Abstract

Dissymmetrical substitution of norcorrole enables the preparation of various norcorrole derivatives as air- and moisture-stable species. Intramolecular charge transfer interactions between electron-donating substituents and the norcorrole core in these norcorroles significantly enhanced their low-energy absorption bands, which were forbidden in symmetrical NiII dimesitylnorcorrole.

Journal

  • Chemical Communications

    Chemical Communications 53(6), 1112-1115, 2017-01-18

    Royal Society of Chemistry

Codes

  • NII Article ID (NAID)
    120006305603
  • Text Lang
    ENG
  • Article Type
    journal article
  • ISSN
    1359-7345
  • Data Source
    IR 
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