Photochemical synthesis of naphthacene and its derivatives for irreversible photo-responsive fluorescent molecules

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Abstract

Highly fluorescent naphthacene derivatives and their photoconvertible precursors were synthesized for irreversibly photo-responsive fluorescent molecules. The fluorescence quantum yields (Φf) of the precursors were less than 0.02, and the precursors can be converted to the highly fluorescent naphthacene derivatives (Φf=0.67?0.70) quantitatively by photo-irradiation.

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