Aromaticity Relocation in Perylene Derivatives upon Two-Electron Oxidation To Form Anthracene and Phenanthrene

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抄録

We prepared perylene dications 12+ and 22+ by using "capped" perylene derivatives, and for the first time, successfully obtained single crystals of a perylene dication 12+ that enabled us to perform its structural analysis. We realized that the substituted aryl groups on perylene control the positions of positive charges, thus the remaining electronic system satisfies Clar's sextet rule toward the highest number of localized sextets. Experimental and theoretical evidence proved that Clar's aromatic π-sextet rule could be applied even for the dicationic perylenes in a very simple way.

収録刊行物

  • 2016-08-12

    WILEY-VCH Verlag

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各種コード

  • NII論文ID(NAID)
    120006334985
  • 本文言語コード
    ENG
  • 資料種別
    journal article
  • ISSN
    1521-3765
  • データ提供元
    IR 
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