有機合成における酸化グラフェン触媒の構造と反応性の相関

• 井坂 琢也

抄録

type:Article

The correlation between the structure and the reactivity of graphene oxide (GO) as catalyst for the organic synthesis in organic and water medium was investigated in terms of base-treatment and thermal reduction by using XPS, FTIR and GC-MS. Highly oxidized GO samples acted as oxidizing reagent in a synthesis reaction of N-benzylidenebenzylamine from benzylamine. However, GO samples act as catalyst after the 1st cycle reaction, where nitrogen-containing functional groups play an important role. In the synthesis reaction for xanthene-derivatives in water medium, base-treated GO samples work as catalyst, where it is suggested that C-O-C and/or C=O relates to the reactivity. Key Words : graphene oxide, chemical activity, chemical structure

収録刊行物

• 法政大学大学院紀要. 理工学・工学研究科編

  法政大学大学院紀要. 理工学・工学研究科編 58 1-2, 2017-03-31

  法政大学大学院理工学・工学研究科

詳細情報

• CRID: 1390572174784393472
• NII論文ID: 120006354215
• NII書誌ID: AA12677220
• ISSN: 21879923
• DOI: 10.15002/00014131
• Web Site: http://hdl.handle.net/10114/13487
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • IRDB
  • CiNii Articles