REGIOSELECTIVITY OF THE INTRAMOLECULAR BIARYL COUPLING REACTION OF 3-SUBSTITUTED PHENYL 2-IODOBENZOATE USING A PALLADIUM REAGENT

• Maeda, Kazuhiro

• Matsukihira, Takuya

• Saga, Shumpei

• Takeuchi, Yasuo

• Harayama, Takashi

• Horino, Yoshikazu

• Abe, Hitoshi

Abstract

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This study investigated the regioselectivity of the intramolecular coupling reaction of the phenyl benzoate derivative which possesses a methyl or methoxy group at the meta-position of the phenoxy moiety. The type of base and the presence/absence of the phosphine ligand influenced the product ratio. A transition state model and the regioselectivity of the reaction are discussed.

Article

Heterocycles 88(1), 621-628.(2014)

Journal

• Heterocycles

  Heterocycles 88 (1), 621-628, 2014

  日本複素環化学研究所

Details

• CRID: 1050001339105911296
• NII Article ID: 120006395306
• HANDLE: 10110/00018078
• Web Site: https://toyama.repo.nii.ac.jp/records/15614
• Text Lang: en
• Article Type: journal article
• Data Source:
  • IRDB
  • CiNii Articles