Acceptorless dehydrogenation of N-heterocycles by supported Pt catalysts

• Moromi, Sondomoyee K.

• Siddiki, S. M. A. H.

• Kon, Kenichi

• Toyao, Takashi

• Shimizu, Ken-ichi

抄録

Pt metal nanoparticles loaded on various supports and carbon-supported various metal catalysts are tested for dehydrogenation of 6-methyl-1,2,3,4- tetrahydroquinoline to 6-methyl-quinoline under oxidant-free conditions. In the 20 types of the catalysts screened, carbon-supported Pt catalyst (Pt/C) shows the highest activity. Pt/C is reusable after the reaction and is effective for dehydrogenation of various N-heterocycles (tetrahydroquinolines and indoline). Pt/C is also effective for hydrogenation of quinoline under 3 bar H-2. The results demonstrate that this catalytic method may be useful for an organic hidride-based hydrogen storage system.

収録刊行物

• Catalysis today

  Catalysis today 281 507-511, 2017-03-01

  Elsevier

キーワード

• Pt nanoparticles
• Dehydrogenation
• N-heterocycles
• Hydrogen storage

詳細情報

• CRID: 1050001339057548416
• NII論文ID: 120006577365
• DOI: 10.1016/j.cattod.2016.06.027
• HANDLE: 2115/72825
• ISSN: 09205861
• Web Site: https://api.elsevier.com/content/article/PII:S0920586116304291?httpAccept=text/xml
• Web Site: https://api.elsevier.com/content/article/PII:S0920586116304291?httpAccept=text/plain
• 本文言語コード: en
• 資料種別: journal article
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