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Abstract

A series of phenanthrene-fused N2O-type boron-dipyrrin complexes (BODIPYs) with various substituents were synthesized. The synthesized BODIPYs show light absorption and emission in the red to near-infrared region due to their extended π-system. Furthermore, the first optical resolution of the N2O-type BODIPY was achieved using the phenyl-substituted complex. The separated enantiomers are stable to racemization at room temperature, and exhibited a Cotton effect in the deep-red region.

Journal

  • Tetrahedron letters

    Tetrahedron letters 59(47), 4149-4152, 2018-11

    Elsevier

Keywords

Codes

  • NII Article ID (NAID)
    120006582796
  • NII NACSIS-CAT ID (NCID)
    AA00861801
  • Text Lang
    ENG
  • Article Type
    journal article
  • ISSN
    0040-4039
  • Data Source
    IR 
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