Photoactivated <i>N</i>‐Acyliminoiodinanes Applied to Amination: an <i>ortho</i>‐Methoxymethyl Group Stabilizes Reactive Precursors

• 小林, 祐輔

  Graduate School of Pharmaceutical Sciences, Kyoto University

• 正門, 宗大

  Graduate School of Pharmaceutical Sciences, Kyoto University

• 竹本, 佳司

  Graduate School of Pharmaceutical Sciences, Kyoto University

書誌事項

タイトル別名

• Photoactivated N-Acyliminoiodinanes Applied to Amination: an ortho-Methoxymethyl Group Stabilizes Reactive Precursors

抄録

N‐Acyliminoiodinanes were characterized for the first time by X‐ray structural analysis. The ortho‐methoxymethyl group and the carbonyl oxygen coordinate to the iodine atom of the iminoiodinane. Activation of the N‐acyliminoiodinane was achieved by photoirradiation at 370 nm, thereby enabling reaction with various silyl enol ethers to give α‐aminoketone derivatives in good to high yield. N‐sulfonyliminoiodinanes bearing ortho substituents were used in photoinduced amination.

収録刊行物

• Angewandte Chemie

  Angewandte Chemie 57 (3), 693-697, 2018-01-15

  Wiley

キーワード

• amination
• hypervalent iodine
• photoreaction

詳細情報

• CRID: 1050282813364819584
• NII論文ID: 120006653113
• NII書誌ID: AA0052535X
• ISSN: 14337851
• ISSN: 15213773
• DOI: 10.1002/anie.201710277
• HANDLE: 2433/243150
• Web Site: https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201710277
• Web Site: https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201710277
• Web Site: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201710277
• 本文言語コード: en
• 資料種別: journal article
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