Palladium-catalyzed Synthesis of Terminal Acetals via Highly Selective Anti-Markovnikov Nucleophilic Attack of Pinacol on Vinylarenes, Allyl Ethers, and 1,5-Dienes

• Yamamoto, Mayumi

• Nakaoka, Sonoe

• Ura, Yasuyuki

• Kataoka, Yasutaka

抄録

type:Article

A palladium-catalyzed reaction of vinylarenes, allyl ethers,and 1,5-dienes with pinacol proceeded via a selective anti-Markovnikov nucleophilic attack to afford corresponding 10 terminal acetals as major products. The bulkiness of pinacol was found to be critical in controlling the regioselectivity.

収録刊行物

• Chemical Communications

  Chemical Communications 48 (8), 1165-1167, 2011-12-12

  Royal Society of Chemistry

詳細情報

• CRID: 1050001338391099776
• NII論文ID: 120006657547
• NII書誌ID: AA11071130
• ISSN: 13597345
• Web Site: http://hdl.handle.net/10935/3095
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles