Effect of mixing temperature on the carbon nanofiller distribution in immiscible blends of polycarbonate and polyolefin

• Fan, Bowen

• Wiwattananukul, Rujirek

• Yamaguchi, Masayuki

Abstract

We studied the selective localization of carbon nanofillers, such as multi-walled carbon nanotube (MWCNT) and graphene nanoplatelet (GNP), in immiscible polymer blends composed of polycarbonate (PC) and polyethylene (PE) or ethylene-propylene copolymer (EPR). It was found that the distribution state of the carbon nanofillers in thecomposites is greatly affected by the mixing temperature and the species of nanofillers. MWCNTs resided in the PE or EPR phase in the composites, which cannot be explained by the difference in the interfacial tension. A similar morphology was detected in the PC/GNP/PE composite prepared at 300 °C. In contrast, the PC/GNP/PE compositeprepared at the low temperature (250 °C) and the PC/GNP/EPR composites have the carbon nanofillers mostly in the PC phase. The selective localization in the PE or EPR phase is attributed to the surface adsorption of PE or EPRchains on the carbon nanofillers, which is more obvious for PE and at the high mixing temperature. These results demonstrate that both the species of carbon nanofillers and the mixing temperature affect the carbon nanofiller distribution in the immiscible blends.

identifier:https://dspace.jaist.ac.jp/dspace/handle/10119/16119

Journal

• European Polymer Journal

  European Polymer Journal 96 295-303, 2017-09-19

  Elsevier

Keywords

• Polycarbonate
• Polyethylene
• Ethylene-Propylene Copolymer
• Carbon Nanofiller
• Polymer Blend

Details

• CRID: 1050001338788194816
• NII Article ID: 120006732080
• ISSN: 00143057
• Web Site: http://hdl.handle.net/10119/16119
• Text Lang: en
• Article Type: journal article
• Data Source:
  • IRDB
  • CiNii Articles