Flavin–Iodine Coupled Organocatalysis for Aerobic Oxidative Direct Sulfenylation of Indoles with Thiols under Mild Conditions

• Ohkado, Ryoma

• Ishikawa, Tatsuro

• Iida, Hiroki

抄録

A unique coupled redox organocatalysis system using flavin and iodine catalysts efficiently promoted the metal-free aerobic oxidative direct sulfenylation of indoles with thiols at ambient temperature without any sacrificial reagents, except environmentally benign molecular oxygen. Biomimetic flavin catalysis plays multiple roles in aerobic oxidative transformations, not only regenerating I2 from in situ generated I−, but also converting thiols into disulfides.

収録刊行物

• Green Chemistry

  Green Chemistry 20 984-988, 2018-02-05

  The Royal Society of Chemistry

キーワード

• Pollution
• Environmental Chemistry

詳細情報

• CRID: 1050002213398876288
• NII論文ID: 120006813710
• ISSN: 14639262
• ISSN: 14639270
• DOI: 10.1039/c8gc00117k
• Web Site: http://ir.lib.shimane-u.ac.jp/49157
• Web Site: http://pubs.rsc.org/en/content/articlepdf/2018/GC/C8GC00117K
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
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