Dual dynamic chirality generated in the assembly of three achiral rods through the three- fold twisting of a macrocycle

• Katoono, Ryo

• Sakamoto, Kazuki

• Suzuki, Takanori

Abstract

We demonstrated dynamic chirality based on assemblies of three achiral rods with a twisted macrocycle. The three-fold twisting of a macrocycle can lead to two different chiral forms with C-2- or D-3-symmetry. Through a transmission of chirality to each dynamic chiral form, a helical-sense preference was successfully induced.

Journal

• Chemical communications

  Chemical communications 55 (38), 5503-5506, 2019-05-11

  Royal Society of Chemistry

Keywords

• Materials Chemistry
• Metals and Alloys
• Surfaces, Coatings and Films
• General Chemistry
• Ceramics and Composites
• Electronic, Optical and Magnetic Materials
• Catalysis

Details

• CRID: 1050566774724665856
• NII Article ID: 120006843069
• DOI: 10.1039/c9cc02226k
• ISSN: 1364548X
• ISSN: 13597345
• HANDLE: 2115/77880
• Web Site: http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC02226K
• Text Lang: en
• Article Type: journal article
• Data Source:
  • IRDB
  • Crossref
  • CiNii Articles
  • KAKEN