Copper-Catalyzed Arylstannylation of Arynes in Sequence

• Tanaka, Hideya

• Kuriki, Hitoshi

• Kubo, Teruhiko

• Osaka, Itaru

• Yoshida, Hiroto

抄録

Copper-catalyzed arylstannylation of arynes has been developed. This transformation enables variously substituted ortho-stannylbiaryls and teraryls to be constructed straightforwardly. An electron-deficient tin center is the key, and thus the single or dual insertion of arynes into arylstannanes is precisely controllable by simply changing the equivalence of aryne precursors.

収録刊行物

• Chemical Communications

  Chemical Communications 55 (46), 6503-6506, 2019-06-11

  Royal Society of Chemistry

詳細情報

• CRID: 1050014791007769984
• NII論文ID: 120006849362
• Web Site: http://ir.lib.hiroshima-u.ac.jp/00048221
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles