Catalytic Enantioselective Methylene C(sp³)−H Amidation of 8‐Alkylquinolines Using a Cp*Rh^III/Chiral Carboxylic Acid System

• Fukagawa, Seiya

• Kojima, Masahiro

• Yoshino, Tatsuhiko

• Matsunaga, Shigeki

書誌事項

タイトル別名

• Catalytic Enantioselective Methylene C(sp(3))-H Amidation of 8-Alkylquinolines Using a Cp*Rh-III/Chiral Carboxylic Acid System

抄録

Catalytic enantioselective directed methylene C(sp(3))-H amidation reactions of 8-alkylquinolines using a Cp*Rh-III/chiral carboxylic acid (CCA) hybrid catalytic system are described. A binaphthyl-based chiral carboxylic acid efficiently differentiates between the enantiotopic methylene C-H bonds, which leads to the formation of C-N bonds with good enantioselectivity.

収録刊行物

• Angewandte chemie-international edition

  Angewandte chemie-international edition 58 (50), 18154-18158, 2019-10-08

  Wiley-Blackwell

キーワード

• asymmetric catalysis
• C-H activation
• chiral carboxylic acid
• quinoline
• rhodium

詳細情報

• CRID: 1050848650332694144
• NII論文ID: 120006890337
• DOI: 10.1002/anie.201911268
• ISSN: 15213773
• ISSN: 14337851
• HANDLE: 2115/79493
• Web Site: https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201911268
• Web Site: https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201911268
• Web Site: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201911268
• Web Site: https://onlinelibrary.wiley.com/doi/am-pdf/10.1002%2Fanie.201911268
• 本文言語コード: en
• 資料種別: journal article
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