Cp*Co^III/Chiral Carboxylic Acid‐Catalyzed Enantioselective 1,4‐Addition Reactions of Indoles to Maleimides

• Kurihara, Takumaru

• Kojima, Masahiro

• Yoshino, Tatsuhiko

• Matsunaga, Shigeki

書誌事項

タイトル別名

• Cp*Co-III/Chiral Carboxylic Acid-Catalyzed Enantioselective 1,4-Addition Reactions of Indoles to Maleimides

抄録

We report enantioselective 1,4-addition reactions of indoles to maleimides via a C2-selective C-H activation catalyzed by an achiral Cp*Co-III/chiral carboxylic acid system. In these reactions, a BINOL-derived chiral carboxylic acid enables the enantioselective reactions as the sole chiral source.

収録刊行物

• Asian journal of organic chemistry

  Asian journal of organic chemistry 9 (3), 368-371, 2019-11-14

  Wiley-Blackwell

キーワード

• C-H activation
• cobalt
• chiral carboxylic acids
• asymmetric 1
• 4-addition
• indoles

詳細情報

• CRID: 1051412328408238720
• NII論文ID: 120006896746
• DOI: 10.1002/ajoc.201900565
• ISSN: 21935815
• ISSN: 21935807
• HANDLE: 2115/79746
• Web Site: https://onlinelibrary.wiley.com/doi/pdf/10.1002/ajoc.201900565
• Web Site: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ajoc.201900565
• 本文言語コード: en
• 資料種別: journal article
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