Air- and moisture-stable Xantphos-ligated palladium dialkyl complex as a precatalyst for cross-coupling reactions

• Takahashi, Rina

• Kubota, Koji

• Ito, Hajime

抄録

Although xantphos has been employed in a variety of palladium-catalyzed cross-coupling reactions, there has been little progress in developing Xantphos-ligated precatalysts. In this report, we describe a Xantphos-ligated palladium dialkyl complex that acts as a powerful precatalyst for C-N, C-S, and C-C cross-coupling reactions. This precatalyst is air- and moisture stable but can be thermally activated in the absence of external reagents. Additionally, potential catalyst inhibitors are not generated during the precatalyst activation. This complex thus represents a convenient alternative to previously reported classes of Xantphos-ligated precatalysts.

収録刊行物

• Chemical communications

  Chemical communications 56 (3), 407-410, 2020-01-11

  Royal Society of Chemistry

詳細情報

• CRID: 1050569015578128000
• NII論文ID: 120006952009
• DOI: 10.1039/c9cc06946a
• ISSN: 1364548X
• ISSN: 13597345
• HANDLE: 2115/80131
• Web Site: http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC06946A
• 本文言語コード: en
• 資料種別: journal article
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