Electrochromism of a bipolar reversible redox-active ferrocene?viologen linked ionic liquid

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A ferrocene-viologen linked “bipolar” type redox-active ionic liquid ([FcC11VC1][TFSI]2) was synthesized as an electrochromic (EC) material that functions without any other additives: solvents, supporting electrolytes and sacrificial agents. The efficiency of a prototype symmetrical EC cell was 70 cm2 C?1 at 1.0 V. The EC process was stable even after over 10?000 potential cycles.

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